Higher Education

Principles of Modern Chemistry, 8th Edition

  • David W. Oxtoby Pomona College
  • H. Pat Gillis University of California - Los Angeles
  • Laurie J. Butler The University of Chicago
  • ISBN-10: 1305079116  |  ISBN-13: 9781305079113
  • 1264 Pages
  • Previous Editions: 2012, 2008, 2003
  • © 2016 | Published
  • College Bookstore Wholesale Price = $255.25
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About

Overview

Long considered the standard for honors and high-level mainstream general chemistry courses, PRINCIPLES OF MODERN CHEMISTRY continues to set the standard as the most modern, rigorous, and chemically and mathematically accurate text on the market. This authoritative text features an "atoms first" approach and thoroughly revised chapters on Quantum Mechanics and Molecular Structure (Chapter 6), Electrochemistry (Chapter 17), and Molecular Spectroscopy and Photochemistry (Chapter 20). In addition, the text utilizes mathematically accurate and artistic atomic and molecular orbital art, and is student friendly without compromising its rigor. End-of-chapter study aids focus on only the most important key objectives, equations and concepts, making it easier for students to locate chapter content, while applications to a wide range of disciplines, such as biology, chemical engineering, biochemistry, and medicine deepen students' understanding of the relevance of chemistry beyond the classroom.

Features and Benefits

  • OWLv2 is the most trusted online learning solution for chemistry. Featuring chemist-developed content, OWLv2 is the only system designed to elevate thinking through Mastery Learning, allowing students to work at their own pace until they understand each concept and skill. Each time a student tries a problem, OWLv2 changes the chemicals, values, and sometimes even the wording of the question to ensure students are learning the concepts and not cheating the system. With detailed, instant feedback and interactive learning resources, students get the help they need when they need it. Now with improved student and instructor tools and greater functionality, OWLv2 is more robust than ever. Discover the power of OWLv2 and take learning to a higher level.
  • AN "ATOMS FIRST" APPROACH places coverage of structure and bonding early in the text (Chapter 4-6), taking students right into the core topics of the course and helping them build a strong conceptual understanding of chemistry.
  • A UNIQUE APPROACH TO LEARNING CHEMICAL PRINCIPLES emphasizes the scientific process from observation to application, placing general chemistry into perspective for serious-minded science and engineering students.
  • MATHEMATICALLY ACCURATE MOLECULAR ORBITAL ART helps students visualize how orbital equations translate into the shapes of the orbitals.
  • A FOCUS ON PROBLEM SOLVING. Problems are grouped into three categories: 1) Paired problems in the first set are grouped by section, with answers to the odd-numbered paired problems collected in Appendix G so students can check their answer to the first problem in a pair before undertaking the second parallel problem. 2) Additional Problems (unpaired) provide further applications of the principles developed in the chapter. 3) Cumulative Problems integrate material from the chapter with topics presented earlier in the book. More challenging problems are integrated throughout the problem sets and are indicated with asterisks.
  • PEDAGOGICALLY IMPORTANT APPENDICES. Appendix A discusses experimental error and scientific notation; Appendix B introduces the SI system of units used throughout the book, describes the methods used for converting units, and provides a brief review of some fundamental principles in physics. Appendix C provides a review of mathematics for general chemistry, including a new section on vectors in Cartesian coordinates. Appendices D, E, and F are compilations of thermodynamic, electrochemical, and physical data, respectively.

Table of Contents

Unit I. Introduction to the Study of Modern Chemistry.
1. The Atom in Modern Chemistry.
2. Chemical Formulas, Equations, and Reaction Yields.
Unit II. Chemical Bonding and Molecular Structure.
3. Atomic Shells and Classical Models of Chemical Bonding.
4. Introduction to Quantum Mechanics.
5. Quantum Mechanics and Atomic Structure.
6. Quantum Mechanics and Molecular Structure.
7. Bonding in Organic Molecules.
8. Bonding in Transition Metal Compounds and Coordination Complexes.
Unit III. Kinetic Molecular Description of the States of Matter.
9. The Gaseous State.
10. Solids, Liquids, and Phase Transitions.
11. Solutions.
Unit IV. Equilibrium in Chemical Reactions.
12. Thermodynamic Processes and Thermochemistry.
13. Spontaneous Processes and Thermodynamic Equilibrium.
14. Chemical Equilibrium.
15. Acid–Base Equilibria.
16. Solubility and Precipitation Equilibria.
17. Electrochemistry.
Unit V. Rates of Chemical and Physical Processes.
18. Chemical Kinetics.
19. Nuclear Chemistry.
20. Molecular Spectroscopy and Photochemistry.
Unit VI. Materials.
21. Structure and Bonding in Solids.
22. Inorganic Materials.
23. Polymeric Materials and Soft Condensed Matter.
Appendix A. Scientific Notation and Experimental Error.
Appendix B. SI Units, Unit Conversions, and Physics for General Chemistry.
Appendix C. Mathematics for General Chemistry.
Appendix D. Standard Chemical Thermodynamic Properties.
Appendix E. Standard Reaction Potentials at 25°C.
Appendix F. Physical Properties of the Elements.
Appendix G. Solutions to the Odd-Numbered Problems.
Index/Glossary.

What's New

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  • The most powerful online learning solution for chemistry is better than ever. OWLv2 now has more flexible student and instructor functionality, new personalized study tools, enhanced integration with learning management systems, and improved analytics. For this course, OWLv2 also includes Quick Prep, an online short course to review key chemistry concepts and essential skills, new iPad-compatible visualizations, tutorials, and simulations, and new Adaptive Study Plans. In addition, Tutors, Visualizations and Simulations have been converted from Flash to HTML, allowing for easier navigation and streamlined grading.
  • Recognizing that in the top colleges and universities that use this text over 90 percent of students taking introductory chemistry have taken a single variable calculus course in high school, or are taking calculus as a co-requisite for the course, we have improved several portions of the text. These revisions include a more quantitative treatment of the forces and potential energy in molecules, dipole moments, molecular collisions, and the Maxwell-Boltzmann distribution of molecular speeds. The concepts of slope and area are introduced in the physical and chemical contexts in which they arise, and differential and integral notation is used in parallel with these concepts. Thus, students with a single-variable calculus background are engaged fully, while students without that background will not be at a disadvantage. Simple vectors are introduced to aid in discussing force and velocity, with a new section in Appendix C covering vectors in Cartesian coordinates.

Alternate Formats

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  • Hybrid Edition

    ISBN-10: 1305395891 | ISBN-13: 9781305395893

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Learning Resource Bundles

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Printed Text + LMS Integrated for OWLv2, 1 term (6 months) Instant Access

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ISBN-10:  1337082104  | ISBN-13:  9781337082105

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Printed Text + OWLv2 with Student Solutions Manual, 4 terms (24 months) Instant Access

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ISBN-10:  1337078670  | ISBN-13:  9781337078672

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This Bundle Includes:

  • Principles of Modern Chemistry
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  • Principles of Modern Chemistry
    List Price = $339.95  | CengageBrain Price = $339.95  | College Bookstore Wholesale Price = $255.25
  • OWLv2, 4 terms (24 months) Instant Access
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Efficacy and Outcomes

Reviews

"I believe it is written well for an honors-level freshman chemistry course; i.e. it covers all of the basic material but in a way that is more thorough and intelligent than other introductory texts."

— Lauren Webb, University of Texas

"Excellent discussion of the basics from a scientific viewpoint and good illustrations of the principles. Excellent figures and example problems. Excellent homework problems."

— Tom Mason, University of California at Los Angeles

"The traditional coverage of atomic and molecular theory has always been a strong point of Principles of Modern Chemistry. My opinion this is the ONLY text on the market that so methodically demonstrates an underlying connectivity between chemical processes, molecular structure, and energetics."

— Michael Topp, University of Pennsylvania

"My opinion this is the ONLY text on the market that so methodically demonstrates an underlying connectivity between chemical processes, molecular structure, and energetics."

— Andrew Pounds, Mercer University

"The greatest strength in this book is the mathematical rigor. Students learn in many ways and some need the mathematics. Too many of the general chemistry textbooks (even honors) seem to be taking out mathematics as a way to 'make the chemistry more understandable' instead of keeping the mathematics in and then describing the mathematics in an intuitive manner. The authors have worked on integrating the mathematics and the qualitative description. This has greatly improved the understandability of concepts."

— Regina Frey, Washington University of St. Louis

Supplements

All supplements have been updated in coordination with the main title. Select the main title's "About" tab, then select "What's New" for updates specific to title's edition.

For more information about these supplements, or to obtain them, contact your Learning Consultant.

Instructor Supplements

Website  (ISBN-10: 1305092309 | ISBN-13: 9781305092303)

Instructor Resource Site: Everything you need for your course in one place! This collection of book-specific lecture and class tools is available online via www.cengage.com/login. Access and download PowerPoint presentations, images, instructor's manual, videos, and more.

Cengage Learning Testing, powered by Cognero Instant Access  (ISBN-10: 1305387554 | ISBN-13: 9781305387553)

Cengage Learning Testing Powered by Cognero is a flexible, online system that allows you to author, edit, and manage test bank content from multiple Cengage Learning solutions as well as create multiple test versions in an instant and deliver tests from your LMS, your classroom or wherever you want.

Student Solutions Manual  (ISBN-10: 1305092279 | ISBN-13: 9781305092273)

Students can prepare for exams and succeed in your chemistry course with this comprehensive solutions manual! Featuring worked-out solutions to every odd-numbered problem in PRINCIPLES OF MODERN CHEMISTRY, 8th Edition, this manual shows students how to approach and solve problems using the same step-by-step explanations found in the textbook examples.

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OWLv2, 1 term (6 months) Instant Access  (ISBN-10: 1305271599 | ISBN-13: 9781305271593)

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OWLv2, 4 terms (24 months) Instant Access  (ISBN-10: 1305271572 | ISBN-13: 9781305271579)

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List Price = $130.00  | CengageBrain Price = $130.00  | College Bookstore Wholesale Price = $130.00

MindLink for OWLv2 6-Months Instant Access  (ISBN-10: 1305399145 | ISBN-13: 9781305399143)

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List Price = $130.00  | CengageBrain Price = $130.00  | College Bookstore Wholesale Price = $130.00

Student Solutions Manual eBook Instant Access  (ISBN-10: 1305395964 | ISBN-13: 9781305395961)

Students can use this ISBN to purchase instant access to this eBook version of the Student Solutions Manual at www.CENGAGEbrain.com. Students can prepare for exams and succeed in your chemistry course with this comprehensive solutions manual! Featuring worked-out solutions to every odd-numbered problem in PRINCIPLES OF MODERN CHEMISTRY, 8th Edition, this manual shows students how to approach and solve problems using the same step-by-step explanations found in the textbook examples.

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Essential Algebra for Chemistry Students  (ISBN-10: 0495013277 | ISBN-13: 9780495013273)

Available for packaging with any CENGAGE textbook, this short book is intended for students who lack confidence and/or competency in the essential mathematics skills necessary to survive in general chemistry. Each chapter focuses on a specific type of skill and has worked-out examples to show how these skills translate to chemical problem solving. This book is also available for students to purchase separately at www.CENGAGEbrain.com.

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The Guide to Surviving General Chemistry  (ISBN-10: 1305391381 | ISBN-13: 9781305391383)

Available packaged with any CENGAGE textbook, this helpful guide is a frontline resource for students who need extra help or want to improve their General Chemistry grade. Written by a student with extensive tutoring experience who understands where students struggle most and using terms that they most relate to and understand, this guide helps students see that they can actually master chemistry concepts. GUIDE TO SURVIVING GENERAL CHEMISTRY includes study tips and example problems with worked out solutions for all topics in general chemistry, and is endorsed by Professor Mark Oram, Ph.D, for accuracy and topic coverage. This book is also available for students to purchase separately at www.CENGAGEbrain.com.

List Price = $26.95  | CengageBrain Price = $26.95  | College Bookstore Wholesale Price = $20.50

Student Supplements

Student Solutions Manual  (ISBN-10: 1305092279 | ISBN-13: 9781305092273)

Prepare for exams and succeed in your chemistry course with this comprehensive solutions manual! Featuring worked-out solutions to every odd-numbered problem in PRINCIPLES OF MODERN CHEMISTRY, 8th Edition, this manual shows you how to approach and solve problems using the same step-by-step explanations found in your textbook examples.

List Price = $141.95  | CengageBrain Price = $141.95  | College Bookstore Wholesale Price = $106.75

OWLv2, 1 term (6 months) Instant Access  (ISBN-10: 1305271599 | ISBN-13: 9781305271593)

If your instructor requires OWLv2 for this course, you can use this ISBN to purchase instant access at www.CENGAGEbrain.com. OWLv2 is the most trusted online learning solution for chemistry, proven to help you get a better grade. Featuring chemist-developed content, OWLv2 is the only system designed to elevate thinking through Mastery Learning, allowing you to work at your own pace until you understand each concept and skill. Each time you try a problem, OWLv2 changes the chemicals, values, and sometimes even the wording of the question to ensure you are learning the concepts and not just doing homework. With detailed, instant feedback and interactive learning resources, you get the help you need when you need it. Now with improved answer entry and input tools, OWLv2 is more robust than ever. Discover the power of OWLv2 and take your learning to a higher level. To learn more, visit www.CENGAGE.com/owlv2 or talk to your instructor.

List Price = $100.00  | CengageBrain Price = $100.00  | College Bookstore Wholesale Price = $100.00

OWLv2, 4 terms (24 months) Instant Access  (ISBN-10: 1305271572 | ISBN-13: 9781305271579)

If your instructor requires OWLv2 for this course, you can use this ISBN to purchase instant access at www.CENGAGEbrain.com. OWLv2 is the most trusted online learning solution for chemistry, proven to help you get a better grade. Featuring chemist-developed content, OWLv2 is the only system designed to elevate thinking through Mastery Learning, allowing you to work at your own pace until you understand each concept and skill. Each time you try a problem, OWLv2 changes the chemicals, values, and sometimes even the wording of the question to ensure you are learning the concepts and not just doing homework. With detailed, instant feedback and interactive learning resources, you get the help you need when you need it. Now with improved answer entry and input tools, OWLv2 is more robust than ever. Discover the power of OWLv2 and take your learning to a higher level. To learn more, visit www.CENGAGE.com/owlv2 or talk to your instructor.

List Price = $130.00  | CengageBrain Price = $130.00  | College Bookstore Wholesale Price = $130.00

MindLink for OWLv2 6-Months Instant Access  (ISBN-10: 1305399145 | ISBN-13: 9781305399143)

Cengage Learning provides Learning Management System (LMS) integration with our MindLinks service. This service is designed to deliver an optimal user experience through the learning management system (LMS) already used by the institution--facilitating learning retention and contributing to better learner outcomes. Our collaboration with LMS industry leaders helps drive advanced features like gradebook integration, while the fluid pedagogical design contributes to more teachable moments.

List Price = $100.00  | College Bookstore Wholesale Price = $100.00

MindLink for OWLv2 24-Months Instant Access  (ISBN-10: 1305399161 | ISBN-13: 9781305399167)

Cengage Learning provides Learning Management System (LMS) integration with our MindLinks service. This service is designed to deliver an optimal user experience through the learning management system (LMS) already used by the institution--facilitating learning retention and contributing to better learner outcomes. Our collaboration with LMS industry leaders helps drive advanced features like gradebook integration, while the fluid pedagogical design contributes to more teachable moments.

List Price = $130.00  | CengageBrain Price = $130.00  | College Bookstore Wholesale Price = $130.00

Student Solutions Manual eBook Instant Access  (ISBN-10: 1305395964 | ISBN-13: 9781305395961)

The eBook version of the Student Solutions Manual. Prepare for exams and succeed in your chemistry course with this comprehensive solutions manual! Featuring worked-out solutions to every odd-numbered problem in PRINCIPLES OF MODERN CHEMISTRY, 8th Edition, this manual shows you how to approach and solve problems using the same step-by-step explanations found in your textbook examples.

List Price = $52.00  | CengageBrain Price = $52.00  | College Bookstore Wholesale Price = $52.00

OWLv2 with Student Solutions Manual, 4 terms (24 months) Instant Access  (ISBN-10: 1305866894 | ISBN-13: 9781305866898)

Develop a deep conceptual understanding of chemistry with PRINCIPLES OF MODERN CHEMISTRY, the textbook that continues to set the standard as the most modern, chemically and mathematically accurate text on the market. Packed with worked examples and exercises and mathematically accurate molecular art--and integrated with the #1 online homework and tutorial system for chemistry--the book is designed throughout to help you succeed in the course. In addition, end-of-chapter study aids focus on only the most important key objectives, equations and concepts to make it easy for you to locate chapter content, and new applications to a wide range of disciplines, such as biology, chemical engineering, biochemistry, and medicine, give you a fascinating look at chemistry's uses beyond the classroom.

List Price = $181.00  | CengageBrain Price = $181.00  | College Bookstore Wholesale Price = $181.00

MindLink for OWLv2 with Student Solutions Manual, 4 terms (24 months) Instant Access  (ISBN-10: 1305866916 | ISBN-13: 9781305866911)

Develop a deep conceptual understanding of chemistry with PRINCIPLES OF MODERN CHEMISTRY, the textbook that continues to set the standard as the most modern, chemically and mathematically accurate text on the market. Packed with worked examples and exercises and mathematically accurate molecular art--and integrated with the #1 online homework and tutorial system for chemistry--the book is designed throughout to help you succeed in the course. In addition, end-of-chapter study aids focus on only the most important key objectives, equations and concepts to make it easy for you to locate chapter content, and new applications to a wide range of disciplines, such as biology, chemical engineering, biochemistry, and medicine, give you a fascinating look at chemistry's uses beyond the classroom.

List Price = $181.00  | CengageBrain Price = $181.00  | College Bookstore Wholesale Price = $181.00

Essential Algebra for Chemistry Students  (ISBN-10: 0495013277 | ISBN-13: 9780495013273)

Available for packaging with any CENGAGE textbook or available separately for a minimal cost at CENGAGEbrain.com, this short book is intended for students who lack confidence and/or competency in the essential mathematics skills necessary to survive in general chemistry. Each chapter focuses on a specific type of skill and has worked-out examples to show how these skills translate to chemical problem solving.

List Price = $60.95  | CengageBrain Price = $60.95  | College Bookstore Wholesale Price = $45.50

The Guide to Surviving General Chemistry  (ISBN-10: 1305391381 | ISBN-13: 9781305391383)

Being a student himself, Michael Rosen knows exactly how it feels when trying to learn difficult concepts. He has extensive experience tutoring General Chemistry and understands where students need help the most. GUIDE TO SURVIVING GENERAL CHEMISTRY is a straight-to-the-point resource that gives you exactly what you need to know, along with the best techniques for learning general chemistry. Endorsed by Professor Mark Oram, Ph.D for accuracy and topic coverage, this text is filled with study tips, example problems, and worked out solutions for all topics in the course This book is the ideal guide for mastering General Chemistry. Available packaged with any CENGAGE textbook or available separately for a minimal cost at CENGAGEbrain.com.

List Price = $26.95  | CengageBrain Price = $26.95  | College Bookstore Wholesale Price = $20.50

Meet the Author

Author Bio

David W. Oxtoby

David W. Oxtoby became the ninth president of Pomona College on July 1, 2003. An internationally noted chemist, he previously served as dean of physical sciences at the University of Chicago. At Pomona, he holds a coterminous appointment as president and professor of chemistry. Before coming to Pomona, he was associated with the University of Chicago for nearly three decades, with brief interludes to serve as a visiting professor at such places as the University of Paris; the University of Bristol in Great Britain; and the University of Sydney in Australia. Oxtoby is a fellow of the American Physical Society and a member of the American Chemical Society and the American Association for the Advancement of Science. After earning his bachelor's degree, summa cum laude, from Harvard University, he went on to earn his Ph.D. at the University of California, Berkeley. As a research chemist, he is author or co-author of more than 165 scientific articles on such subjects as light scattering, chemical reaction dynamics and phase transitions. In addition to co-authoring Principles of Modern Chemistry and Chemistry: Science of Change, he has received fellowships from the Guggenheim, von Humboldt, Dreyfus, Sloan, Danforth and National Science foundations.

H. Pat Gillis

H.P. Gillis conducts experimental research in the physical chemistry of electronic materials, emphasizing phenomena at solid surfaces and interfaces. Dr. Gillis received his B.S. (Chemistry and Physics) at Louisiana State University and his Ph.D. (Chemical Physics) at The University of Chicago. After postdoctoral research at the University of California-Los Angeles and 10 years with the technical staff at Hughes Research Laboratories in Malibu, California, Dr. Gillis joined the faculty of Georgia Institute of Technology. Dr. Gillis moved to University of California-Los Angeles, where he currently serves as Adjunct Professor of Materials Science and Engineering. He has taught courses in general chemistry, physical chemistry, quantum mechanics, surface science, and materials science at UCLA and at Georgia Institute of Technology.

Laurie J. Butler

Laurie J. Butler received her B.S. at the Massachusetts Institute of Technology, and her Ph.D. at the University of California, Berkeley. After postdoctoral research at the University of Wisconsin, she joined the faculty at The University of Chicago, where she has been a professor since 1987. Professor Butler's research investigates the fundamental inter- and intramolecular forces that drive the course of chemical reactions. Much of her recent work investigates classes of important chemical reactions where the breakdown of the Born-Oppenheimer approximation (the inability of the electronic wavefunction to readjust rapidly enough during the nuclear dynamics) near the transition state alters the dynamics and markedly reduces the reaction rate. She has been an Alfred P. Sloan Fellow and a Camille and Henry Dreyfus Teacher-Scholar, and was awarded the Llewellyn John and Harriet Manchester Quantrell Award for Excellence in Undergraduate Teaching at The University of Chicago.